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Peptide Cyclization and Cyclodimerization by Cu(I)-Mediated Azide-Alkyne Cycloaddition

Head-to-tail cyclodimerization of resin-bound oligopeptides bearing azide and alkyne groups occurs readily by 1,3-dipolar cycloaddition upon treatment with Cu(I). The process was found to be independent of peptide sequence, sensitive to the proximity of the alkyne to the resin, sensitive to solvent...

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Autors principals: Jagasia, Reshma, Holub, Justin M., Bollinger, Markus, Kirshenbaum, Kent, Finn, M.G.
Format: Artigo
Idioma:Inglês
Publicat: 2009
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2677176/
https://ncbi.nlm.nih.gov/pubmed/19309103
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo802097m
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