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Readily Available Highly Active [Ti]-Adamantyl-BINOL Catalysts for the Enantioselective Alkylation of Aldehydes

[Image: see text] A series of enantiopure (R)-adamantyl 1,1′-binaphthalene-2,2′-diols were successfully synthesized in a straightforward one-step reaction from commercial products with excellent overall yields. The activity of chiral titanium catalyst derived from (R)-3,6,6′-tri(adamantan-1-yl)-[1,1...

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Detalhes bibliográficos
Publicado no:ACS Omega
Main Authors: Navarro, Rodrigo, Monterde, Cristina, Iglesias, Marta, Sánchez, Félix
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2018
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6641534/
https://ncbi.nlm.nih.gov/pubmed/31457961
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.7b02013
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