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Valence-to-Core X-ray Emission Spectroscopy as a Probe of O-O Bond Activation in Cu(2)O(2) Complexes
Valence-to-Core (VtC) X-ray emission spectroscopy (XES) was used to directly detect the presence of an O-O bond in a complex comprising the [Cu(2)(II)(µ-η(2):η(2)-O(2))](2+) core relative to its isomer with a cleaved O-O bond having a [Cu(III)(2)(µ-O)(2)](2+) unit. The experimental studies are compl...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6615971/ https://ncbi.nlm.nih.gov/pubmed/30994976 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201903749 |
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