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Valence-to-Core X-ray Emission Spectroscopy as a Probe of O-O Bond Activation in Cu(2)O(2) Complexes

Valence-to-Core (VtC) X-ray emission spectroscopy (XES) was used to directly detect the presence of an O-O bond in a complex comprising the [Cu(2)(II)(µ-η(2):η(2)-O(2))](2+) core relative to its isomer with a cleaved O-O bond having a [Cu(III)(2)(µ-O)(2)](2+) unit. The experimental studies are compl...

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Xehetasun bibliografikoak
Argitaratua izan da:Angew Chem Int Ed Engl
Egile Nagusiak: Cutsail, George E., Gagnon, Nicole L., Spaeth, Andrew D., Tolman, William B., DeBeer, Serena
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2019
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC6615971/
https://ncbi.nlm.nih.gov/pubmed/30994976
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201903749
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