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Calcium Valence-to-Core X-ray Emission Spectroscopy: A Sensitive Probe of Oxo Protonation in Structural Models of the Oxygen-Evolving Complex

[Image: see text] Calcium is an abundant, nontoxic metal that finds many roles in synthetic and biological systems including the oxygen-evolving complex (OEC) of photosystem II. Characterization methods for calcium centers, however, are underdeveloped compared to those available for transition metal...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Mathe, Zachary, Pantazis, Dimitrios A., Lee, Heui Beom, Gnewkow, Richard, Van Kuiken, Benjamin E., Agapie, Theodor, DeBeer, Serena
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2019
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6891804/
https://ncbi.nlm.nih.gov/pubmed/31743026
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b02866
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