Total Synthesis of an Immunogenic Trehalose Phospholipid from Salmonella Typhi and Elucidation of Its sn-Regiochemistry by Mass Spectrometry

[Image: see text] Diphosphatidyltrehalose (diPT) is an immunogenic glycolipid, recently isolated from Salmonella Typhi. Despite rigorous structure elucidation, the sn-position of the acyl chains on the glycerol backbone had not been unequivocally established. A stereoselective synthesis of diPT and...

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Bibliografische gegevens
Gepubliceerd in:Org Lett
Hoofdauteurs: Mishra, Vivek K., Buter, Jeffrey, Blevins, Molly S., Witte, Martin D., Van Rhijn, Ildiko, Moody, D. Branch, Brodbelt, Jennifer S., Minnaard, Adriaan J.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: American Chemical Society 2019
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6614791/
https://ncbi.nlm.nih.gov/pubmed/31247773
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b01725
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