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Enantiodivergent Pd-catalyzed C–C bond formation enabled through ligand parameterization

Despite the enormous potential for the use of stereospecific cross-coupling reactions to rationally manipulate the three-dimensional structure of organic molecules, the factors that control the transfer of stereochemistry in these reactions remain poorly understood. Herein we report a mechanistic an...

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Bibliografske podrobnosti
izdano v:Science
Main Authors: Zhao, Shibin, Gensch, Tobias, Murray, Benjamin, Niemeyer, Zachary L., Sigman, Matthew S., Biscoe, Mark R.
Format: Artigo
Jezik:Inglês
Izdano: 2018
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6613548/
https://ncbi.nlm.nih.gov/pubmed/30237245
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aat2299
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