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Ni-catalyzed deaminative cross-electrophile coupling of Katritzky salts with halides via C─N bond activation

The reductive cross-coupling of sp(3)-hybridized carbon centers represents great synthetic values and insurmountable challenges. In this work, we report a nickel-catalyzed deaminative cross-electrophile coupling reaction to construct C(sp)─C(sp(3)), C(sp(2))─C(sp(3)), and C(sp(3))─C(sp(3)) bonds. A...

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Detalhes bibliográficos
Publicado no:Sci Adv
Main Authors: Ni, Shengyang, Li, Chun-Xiao, Mao, Yu, Han, Jianlin, Wang, Yi, Yan, Hong, Pan, Yi
Formato: Artigo
Idioma:Inglês
Publicado em: American Association for the Advancement of Science 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6598763/
https://ncbi.nlm.nih.gov/pubmed/31259244
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/sciadv.aaw9516
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