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Nickel-Catalyzed Coupling Reactions of Alkyl Electrophiles, Including Unactivated Tertiary Halides, to Generate Carbon–Boron Bonds

Through the use of a catalyst formed in situ from NiBr(2)(•)diglyme and a pybox ligand (both of which are commercially available), we have achieved our first examples of coupling reactions of unactivated tertiary alkyl electrophiles, as well as our first success with nickel-catalyzed couplings that...

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Hlavní autoři: Dudnik, Alexander S., Fu, Gregory C.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3384763/
https://ncbi.nlm.nih.gov/pubmed/22668072
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja304068t
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