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Nickel-Catalyzed Coupling Reactions of Alkyl Electrophiles, Including Unactivated Tertiary Halides, to Generate Carbon–Boron Bonds

Through the use of a catalyst formed in situ from NiBr(2)(•)diglyme and a pybox ligand (both of which are commercially available), we have achieved our first examples of coupling reactions of unactivated tertiary alkyl electrophiles, as well as our first success with nickel-catalyzed couplings that...

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Bibliografiske detaljer
Main Authors: Dudnik, Alexander S., Fu, Gregory C.
Format: Artigo
Sprog:Inglês
Udgivet: 2012
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3384763/
https://ncbi.nlm.nih.gov/pubmed/22668072
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja304068t
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