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Nickel-Catalyzed Carbon–Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations

The first Suzuki cross-couplings of unactivated tertiary alkyl electrophiles are described, employing a readily accessible catalyst (NiBr(2)(·)-diglyme/4,4′-di-t-butyl-2,2′-bipyridine, both commercially available); this also represents the initial example of the use of a Group 10 catalyst to cross-c...

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Detalhes bibliográficos
Main Authors: Zultanski, Susan L., Fu, Gregory C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3547142/
https://ncbi.nlm.nih.gov/pubmed/23281960
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja311669p
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