Chargement en cours...
Chemical Consequences of the Mechanical Bond: A Tandem Active Template‐Rearrangement Reaction
We report the unexpected discovery of a tandem active template CuAAC‐rearrangement process, in which N(2) is extruded on the way to the 1,2,3‐triazole product to give instead acrylamide rotaxanes. Mechanistic investigations suggest this process is dictated by the mechanical bond, which stabilizes th...
Enregistré dans:
| Publié dans: | Angew Chem Int Ed Engl |
|---|---|
| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
John Wiley and Sons Inc.
2019
|
| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6589916/ https://ncbi.nlm.nih.gov/pubmed/30600892 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201813950 |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|