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Synthesis of nucleoside analogs from hydrazine derivatives

Reaction of 6-hydrazino-l,3-dimethyluracil (1) with glycosyl isothiocyanates (2a,b,c) gave the glycosyl thiosemicarbazides (3a,b,c) in good yield, which were cyclized to pyrimidothiadiazines (5a,b,c) with NBS oxidation. And 5a,b,c were converted to pyrazolopyrimidines (6a,b,c) by thermal desulfuriza...

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Vydáno v:Nucleic Acids Res
Hlavní autoři: Ogura, Haruo, Takahashi, Hiroshi, Sakaguchi, Masakazu
Médium: Artigo
Jazyk:Inglês
Vydáno: Oxford University Press 1978
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6581323/
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1093/nar/1.suppl_2.s251
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