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Synthesis of nucleoside analogs from hydrazine derivatives

Reaction of 6-hydrazino-l,3-dimethyluracil (1) with glycosyl isothiocyanates (2a,b,c) gave the glycosyl thiosemicarbazides (3a,b,c) in good yield, which were cyclized to pyrimidothiadiazines (5a,b,c) with NBS oxidation. And 5a,b,c were converted to pyrazolopyrimidines (6a,b,c) by thermal desulfuriza...

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Bibliografische gegevens
Gepubliceerd in:Nucleic Acids Res
Hoofdauteurs: Ogura, Haruo, Takahashi, Hiroshi, Sakaguchi, Masakazu
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Oxford University Press 1978
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6581323/
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1093/nar/1.suppl_2.s251
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