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Synthesis of nucleoside analogs from hydrazine derivatives

Reaction of 6-hydrazino-l,3-dimethyluracil (1) with glycosyl isothiocyanates (2a,b,c) gave the glycosyl thiosemicarbazides (3a,b,c) in good yield, which were cyclized to pyrimidothiadiazines (5a,b,c) with NBS oxidation. And 5a,b,c were converted to pyrazolopyrimidines (6a,b,c) by thermal desulfuriza...

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Detalhes bibliográficos
Publicado no:Nucleic Acids Res
Main Authors: Ogura, Haruo, Takahashi, Hiroshi, Sakaguchi, Masakazu
Formato: Artigo
Idioma:Inglês
Publicado em: Oxford University Press 1978
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6581323/
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1093/nar/1.suppl_2.s251
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