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Stable radical versus reversible σ-bond formation of (porphyrinyl)dicyanomethyl radicals
(Porphyrinyl)dicyanomethyl radicals were produced by oxidation of dicyanomethyl-substituted porphyrins with PbO(2). These radicals constitute a rare example displaying stable radical versus dynamic covalent chemistry (DCC) depending upon the substitution position of the dicyanomethyl radical. meso-D...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Royal Society of Chemistry
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6566382/ https://ncbi.nlm.nih.gov/pubmed/31360409 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01631g |
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