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Highly planar diarylamine-fused porphyrins and their remarkably stable radical cations

Oxidative fusion reactions of meso-phenoxazino Ni(ii) porphyrin were found to be temperature dependent, giving rise to either a doubly phenylene-fused product at room temperature or a singly phenoxazine-fused product at 70 °C. The latter was further oxidized to a doubly phenoxazine-fused Ni(ii) porp...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Fukui, Norihito, Cha, Wonhee, Shimizu, Daiki, Oh, Juwon, Furukawa, Ko, Yorimitsu, Hideki, Kim, Dongho, Osuka, Atsuhiro
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5308406/
https://ncbi.nlm.nih.gov/pubmed/28451165
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02721k
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