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Effective stabilization of a planar phosphorus(iii) center embedded in a porphyrin-based fused aromatic skeleton
Organophosphorus(iii) compounds usually take on stable pyramidal structures with a large inversion barrier of 30–35 kcal mol(–1). In contrast, diphenylphosphine-fused Ni(ii) porphyrin, where the phosphorus atom is directly attached at the meso-position and embedded in a rigid skeleton, exhibits a co...
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| Publicado no: | Chem Sci |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5857933/ https://ncbi.nlm.nih.gov/pubmed/29568471 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03882h |
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