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A new face of phenalenyl-based radicals in the transition metal-free C–H arylation of heteroarenes at room temperature: trapping the radical initiator via C–C σ-bond formation

The radical-mediated transition metal-free approach for the direct C–H bond functionalization of arenes is considered as a cost effective alternative to transition metal-based catalysis. An organic ligand-based radical plays a key role by generating an aryl radical which undergoes a subsequent funct...

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Bibliografski detalji
Izdano u:Chem Sci
Glavni autori: Ahmed, Jasimuddin, P, Sreejyothi, Vijaykumar, Gonela, Jose, Anex, Raj, Manthan, Mandal, Swadhin K.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2017
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Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5674448/
https://ncbi.nlm.nih.gov/pubmed/29163916
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02661g
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