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Reversible carbon–boron bond formation at platinum centers through σ-BH complexes

A reversible carbon–boron bond formation has been observed in the reaction of the coordinatively unsaturated, cyclometalated, Pt(ii) complex [Pt(I(t)Bu(i)Pr′)(I(t)Bu(i)Pr)][BAr(F)], 1, with tricoordinated boranes HBR(2). X-ray diffraction studies provided structural snapshots of the sequence of reac...

詳細記述

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書誌詳細
出版年:Chem Sci
主要な著者: Ríos, Pablo, Martín-de la Calle, Rocío, Vidossich, Pietro, Fernández-de-Córdova, Francisco José, Lledós, Agustí, Conejero, Salvador
フォーマット: Artigo
言語:Inglês
出版事項: The Royal Society of Chemistry 2020
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179255/
https://ncbi.nlm.nih.gov/pubmed/34163924
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05522k
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