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Catalytic Hydrothiolation: Counter-ion Controlled Regioselectivity
In this article, we expand upon the catalytic hydrothiolation of 1,3-dienes to afford either allylic or homoallylic sulfides with high regiocontrol. Mechanistic studies support a pathway where regioselectivity is dictated by the choice of counter-ion associated with the Rh-center. Non-coordinating c...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2019
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6563821/ https://ncbi.nlm.nih.gov/pubmed/30735362 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b11395 |
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