A Nonheme Thiolate-ligated Cobalt Superoxo Complex: Synthesis and Spectroscopic Characterization, Computational Studies, and Hydrogen Atom Abstraction Reactivity

The synthesis and characterization of a Co(II) dithiolato complex Co(M(e3)TACN)(S(2)SiMe(2)) (1) is reported. Reaction of 1 with O(2) generates a rare thiolate-ligated cobalt-superoxo species Co(O(2))(M(e3)TACN)(S(2)SiMe(2)) (2) that was characterized spectroscopically and structurally by resonance...

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Veröffentlicht in:J Am Chem Soc
Hauptverfasser: Gordon, Jesse B., Vilbert, Avery C., Siegler, Maxime A., Lancaster, Kyle M., Moënne-Loccoz, Pierre, Goldberg, David P.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2019
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6556537/
https://ncbi.nlm.nih.gov/pubmed/30776222
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b13134
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