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A Nonheme Thiolate-ligated Cobalt Superoxo Complex: Synthesis and Spectroscopic Characterization, Computational Studies, and Hydrogen Atom Abstraction Reactivity
The synthesis and characterization of a Co(II) dithiolato complex Co(M(e3)TACN)(S(2)SiMe(2)) (1) is reported. Reaction of 1 with O(2) generates a rare thiolate-ligated cobalt-superoxo species Co(O(2))(M(e3)TACN)(S(2)SiMe(2)) (2) that was characterized spectroscopically and structurally by resonance...
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| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6556537/ https://ncbi.nlm.nih.gov/pubmed/30776222 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b13134 |
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