Umpolung α-Silylation of Cyclopropyl Acetates via Low-Temperature Catalytic C–C Activation

We report a redox-neutral, catalytic C–C activation of cyclopropyl acetates to produce silicon-containing five-membered heterocycles in a highly region-and chemoselective fashion. The umpolung α-selective silylation leading to dioxasilolanes is opposed to contemporary β-selective C–C functionalizati...

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Vydáno v:ACS Catal
Hlavní autoři: Avullala, Thirupataiah, Asgari, Parham, Hua, Yuanda, Bokka, Apparao, Ridlen, Shawn G., Yum, Kyungsuk, Dias, H. V. Rasika, Jeon, Junha
Médium: Artigo
Jazyk:Inglês
Vydáno: 2018
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6550485/
https://ncbi.nlm.nih.gov/pubmed/31179157
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b04252
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