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Catalytic Reductive ortho-C–H Silylation of Phenols with Traceless, Versatile Acetal Directing Groups and Synthetic Applications of Dioxasilines

A new, highly selective, bond functionalization strategy, achieved via relay of two transition metal catalysts and the use of traceless acetal directing groups, has been employed to provide facile formation of C–Si bonds and concomitant functionalization of a silicon group in a single vessel. Specif...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Hua, Yuanda, Asgari, Parham, Avullala, Thirupataiah, Jeon, Junha
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5103641/
https://ncbi.nlm.nih.gov/pubmed/27265033
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04018
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