Catalytic hydrogen atom transfer from hydrosilanes to vinylarenes for hydrosilylation and polymerization

Because of the importance of hydrogen atom transfer (HAT) in biology and chemistry, there is increased interest in new strategies to perform HAT in a sustainable manner. Here, we describe a sustainable, net redox-neutral HAT process involving hydrosilanes and alkali metal Lewis base catalysts — elim...

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Pubblicato in:Nat Catal
Autori principali: Asgari, Parham, Hua, Yuanda, Bokka, Apparao, Thiamsiri, Chanachon, Prasitwatcharakorn, Watcharapon, Karedath, Ashif, Chen, Xin, Sardar, Sinjinee, Yum, Kyungsuk, Leem, Gyu, Pierce, Brad S., Nam, Kwangho, Gao, Jiali, Jeon, Junha
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2019
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6711469/
https://ncbi.nlm.nih.gov/pubmed/31460492
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41929-018-0217-z
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