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Enantioselective α-Allylation of Acyclic Esters using B(pin)-Substituted Electrophiles: Independent Regulation of Stereocontrol Elements via Cooperative Pd/Lewis Base Catalysis

Cooperation between Lewis base and Pd catalysts enables the direct enantioselective α-functionalization of aryl and vinyl acetic acid esters using a bifunctional B(pin)-substituted electrophile. Critical to the success of this method was the recognition that both catalysts could control the necessar...

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Vydáno v:Chemistry
Hlavní autoři: Scaggs, W. Rush, Snaddon, Thomas N.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2018
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6515920/
https://ncbi.nlm.nih.gov/pubmed/30011357
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201803543
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