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Traversing Steric Limitations via Cooperative Lewis Base/Pd Catalysis: An Enantioselective Synthesis of α-Branched Esters using 2-Substituted Electrophiles
Cooperative catalysis enables the direct enantioselective α-allylation of linear prochiral esters using 2-substituted allyl electrophiles. Critical to the successful development of the method was the recognition that metal-centered reactivity and the source of enantiocontrol are independent. This fe...
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| Vydáno v: | Angew Chem Int Ed Engl |
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| Hlavní autoři: | , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2018
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6038818/ https://ncbi.nlm.nih.gov/pubmed/29701289 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201803277 |
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