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Enantioselective α-Benzylation of Acyclic Esters Using π-Extended Electrophiles
The first asymmetric cooperative Lewis base/palladium catalyzed benzylic alkylation of acyclic esters is reported. This reaction proceeds via stereodefined C1-ammonium enolate nucleophiles. Critical to its success was the identification of benzylic phosphate electrophiles, which were uniquely reacti...
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| izdano v: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2018
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6499373/ https://ncbi.nlm.nih.gov/pubmed/30011353 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201806742 |
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