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Ketyl radical reactivity via atom transfer catalysis
Single-electron reduction of a carbonyl to a ketyl enables access to a polarity-reversed platform of reactivity for this cornerstone functional group. However, the synthetic utility of the ketyl radical is hindered by the strong reductants necessary for its generation, which also limit its reactivit...
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| Publié dans: | Science |
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| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6504239/ https://ncbi.nlm.nih.gov/pubmed/30309953 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aau1777 |
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