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Substrate Conformation Correlates with the Outcome of Hyoscyamine 6β-Hydroxylase Catalyzed Oxidation Reactions

Hyoscyamine 6β-hydroxylase (H6H) is an α-ketoglutarate dependent mononuclear nonheme iron enzyme that catalyzes C6-hydroxylation of hyoscyamine and oxidative cyclization of the resulting product to give the oxirane natural product scopolamine. Herein, the chemistry of H6H is investigated using hyosc...

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Detaylı Bibliyografya
Yayımlandı:J Am Chem Soc
Asıl Yazarlar: Ushimaru, Richiro, Ruszczycky, Mark W., Chang, Wei-chen, Yan, Feng, Liu, Yung-nan, Liu, Hung-wen
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2018
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6488034/
https://ncbi.nlm.nih.gov/pubmed/29870653
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b03729
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