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Application of Threonine Aldolases for the Asymmetric Synthesis of α‐Quaternary α‐Amino Acids
We report the synthesis of diverse β‐hydroxy‐α,α‐dialkyl‐α‐amino acids with perfect stereoselectivity for the α‐quaternary center through the action of l‐ and d‐specific threonine aldolases. A wide variety of aliphatic and aromatic aldehydes were accepted by the enzymes and conversions up to >80 ...
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| 發表在: | ChemCatChem |
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| Main Authors: | , , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
John Wiley and Sons Inc.
2018
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6485451/ https://ncbi.nlm.nih.gov/pubmed/31057675 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cctc.201800611 |
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