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Successive Nucleophilic and Electrophilic Allylation for The Catalytic Enantioselective Synthesis of 2,4-Disubstituted Pyrrolidines

Successive nucleophilic and electrophilic allylation mediated by the bis-Boc-carbonate derived from 2-methylene−1,3-propane diol enables formation of enantiomerically enriched 2,4-disubstituted pyrrolidines. An initial enantioselective iridium-catalyzed transfer hydrogenative carbonyl C-allylation i...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Luo, Guoshun, Xiang, Ming, Krische, Michael J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6475487/
https://ncbi.nlm.nih.gov/pubmed/30816719
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b00508
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