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T(1) Population as the Driver of Excited‐State Proton‐Transfer in 2‐Thiopyridone
Excited‐state proton transfer (ESPT) is a fundamental process in biomolecular photochemistry, but its underlying mediators often evade direct observation. We identify a distinct pathway for ESPT in aqueous 2‐thiopyridone, by employing transient N 1s X‐ray absorption spectroscopy and multi‐configurat...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6470867/ https://ncbi.nlm.nih.gov/pubmed/30452789 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201804166 |
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