T(1) Population as the Driver of Excited‐State Proton‐Transfer in 2‐Thiopyridone

Excited‐state proton transfer (ESPT) is a fundamental process in biomolecular photochemistry, but its underlying mediators often evade direct observation. We identify a distinct pathway for ESPT in aqueous 2‐thiopyridone, by employing transient N 1s X‐ray absorption spectroscopy and multi‐configurat...

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Bibliographic Details
Published in:Chemistry
Main Authors: Eckert, Sebastian, Norell, Jesper, Jay, Raphael M., Fondell, Mattis, Mitzner, Rolf, Odelius, Michael, Föhlisch, Alexander
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2019
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6470867/
https://ncbi.nlm.nih.gov/pubmed/30452789
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201804166
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