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Covalency‐Driven Preservation of Local Charge Densities in a Metal‐to‐Ligand Charge‐Transfer Excited Iron Photosensitizer

Covalency is found to even out charge separation after photo‐oxidation of the metal center in the metal‐to‐ligand charge‐transfer state of an iron photosensitizer. The σ‐donation ability of the ligands compensates for the loss of iron 3d electronic charge, thereby upholding the initial metal charge...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Jay, Raphael M., Eckert, Sebastian, Vaz da Cruz, Vinícius, Fondell, Mattis, Mitzner, Rolf, Föhlisch, Alexander
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6771958/
https://ncbi.nlm.nih.gov/pubmed/31145507
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201904761
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