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Accelerating slow excited state proton transfer

Visible light excitation of the ligand-bridged assembly [(bpy)(2)Ru(a)(II)(L)Ru(b)(II)(bpy)(OH(2))(4+)] (bpy is 2,2′-bipyridine; L is the bridging ligand, 4-phen-tpy) results in emission from the lowest energy, bridge-based metal-to-ligand charge transfer excited state (L(−•))Ru(b)(III)-OH(2) with a...

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Detalhes bibliográficos
Main Authors: Stewart, David J., Concepcion, Javier J., Brennaman, M. Kyle, Binstead, Robert A., Meyer, Thomas J.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3549109/
https://ncbi.nlm.nih.gov/pubmed/23277551
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1220742110
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