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Direct Catalytic Asymmetric Synthesis of trifluoromethylated γ-Amino Esters/Lactones via Umpolung Strategy
Enabled by the discovery of new cinchinium salts and co-additives, a direct and efficient asymmetric access to trifluoromethylated γ-amino esters/lactones has been realized through the enantioselective and diastereoselective umpolung reaction of trifluoromethyl imines with acrylates or α,β-unsaturat...
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| Publicado no: | J Org Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6467775/ https://ncbi.nlm.nih.gov/pubmed/30543752 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b02893 |
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