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Phosphothreonine (pThr)–Based Multifunctional Peptide Catalysis for Asymmetric Baeyer–Villiger Oxidations of Cyclobutanones

Biologically inspired phosphothreonine (pThr)-embedded peptides that function as chiral Brønsted acid catalysts for enantioselective Baeyer–Villiger oxidations (BV) of cyclobutanones with aqueous H(2)O(2) are reported herein. Complementary to traditional BINOL-derived chiral phosphoric acids (CPAs),...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Featherston, Aaron L., Shugrue, Christopher R., Mercado, Brandon Q., Miller, Scott J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6467539/
https://ncbi.nlm.nih.gov/pubmed/31007966
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b04132
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