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Phosphothreonine as a Catalytic Residue in Peptide-Mediated Asymmetric Transfer Hydrogenations of 8-Aminoquinolines()
We report that phosphothreonine (pThr), upon insertion into peptides, constitutes a new class of chiral phosphoric acid (CPA) catalyst. To demonstrate these phosphopeptides’ potential as asymmetric catalysts, we describe enantioselective transfer hydrogenations of a previously unexplored substrate c...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4628550/ https://ncbi.nlm.nih.gov/pubmed/26246129 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505898 |
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