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Phosphothreonine (pThr)–Based Multifunctional Peptide Catalysis for Asymmetric Baeyer–Villiger Oxidations of Cyclobutanones
Biologically inspired phosphothreonine (pThr)-embedded peptides that function as chiral Brønsted acid catalysts for enantioselective Baeyer–Villiger oxidations (BV) of cyclobutanones with aqueous H(2)O(2) are reported herein. Complementary to traditional BINOL-derived chiral phosphoric acids (CPAs),...
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| Published in: | ACS Catal |
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| Main Authors: | , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6467539/ https://ncbi.nlm.nih.gov/pubmed/31007966 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b04132 |
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