Snapshots of Enzymatic Baeyer-Villiger Catalysis: OXYGEN ACTIVATION AND INTERMEDIATE STABILIZATION

Baeyer-Villiger monooxygenases catalyze the oxidation of carbonylic substrates to ester or lactone products using NADPH as electron donor and molecular oxygen as oxidative reactant. Using protein engineering, kinetics, microspectrophotometry, crystallography, and intermediate analogs, we have captur...

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Bibliographic Details
Main Authors: Orru, Roberto, Dudek, Hanna M., Martinoli, Christian, Torres Pazmiño, Daniel E., Royant, Antoine, Weik, Martin, Fraaije, Marco W., Mattevi, Andrea
Format: Artigo
Language:Inglês
Published: American Society for Biochemistry and Molecular Biology 2011
Subjects:
Enzymology
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3190734/
https://ncbi.nlm.nih.gov/pubmed/21697090
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M111.255075
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