Snapshots of Enzymatic Baeyer-Villiger Catalysis: OXYGEN ACTIVATION AND INTERMEDIATE STABILIZATION

Baeyer-Villiger monooxygenases catalyze the oxidation of carbonylic substrates to ester or lactone products using NADPH as electron donor and molecular oxygen as oxidative reactant. Using protein engineering, kinetics, microspectrophotometry, crystallography, and intermediate analogs, we have captur...

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Detalhes bibliográficos
Main Authors: Orru, Roberto, Dudek, Hanna M., Martinoli, Christian, Torres Pazmiño, Daniel E., Royant, Antoine, Weik, Martin, Fraaije, Marco W., Mattevi, Andrea
Formato: Artigo
Idioma:Inglês
Publicado em: American Society for Biochemistry and Molecular Biology 2011
Assuntos:
Enzymology
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3190734/
https://ncbi.nlm.nih.gov/pubmed/21697090
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M111.255075
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