Snapshots of Enzymatic Baeyer-Villiger Catalysis: OXYGEN ACTIVATION AND INTERMEDIATE STABILIZATION

Baeyer-Villiger monooxygenases catalyze the oxidation of carbonylic substrates to ester or lactone products using NADPH as electron donor and molecular oxygen as oxidative reactant. Using protein engineering, kinetics, microspectrophotometry, crystallography, and intermediate analogs, we have captur...

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Autori principali: Orru, Roberto, Dudek, Hanna M., Martinoli, Christian, Torres Pazmiño, Daniel E., Royant, Antoine, Weik, Martin, Fraaije, Marco W., Mattevi, Andrea
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Society for Biochemistry and Molecular Biology 2011
Soggetti:
Enzymology
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3190734/
https://ncbi.nlm.nih.gov/pubmed/21697090
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M111.255075
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