Metallaphotoredox Difluoromethylation of Aryl Bromides

Herein we report a convenient and broadly applicable strategy for the difluoromethylation of aryl bromides via metallaphotoredox catalysis. Bromodifluoromethane, a simple and commercial alkyl halide, is harnessed as an effective source of difluoromethyl radical via silyl radical-mediated halogen abs...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Bacauanu, Vlad, Cardinal, Sébastien, Yamauchi, Motoshi, Kondo, Masaru, Fernández, David F., Remy, Richard, MacMillan, David W. C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6460465/
https://ncbi.nlm.nih.gov/pubmed/30067304
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201807629
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