Effects of the Metal Ion on the Mechanism of Phosphodiester Hydrolysis Catalyzed by Metal-Cyclen Complexes

In this study, mechanisms of phosphodiester hydrolysis catalyzed by six di- and tetravalent metal-cyclen (M-C) complexes (Zn-C, Cu-C, Co-C, Ce-C, Zr-C and Ti-C) have been investigated using DFT calculations. The activities of these complexes were studied using three distinct mechanisms: (1) direct a...

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Bibliografiska uppgifter
I publikationen:Front Chem
Huvudupphovsmän: Hu, Qiaoyu, Jayasinghe-Arachchige, Vindi M., Zuchniarz, Joshua, Prabhakar, Rajeev
Materialtyp: Artigo
Språk:Inglês
Publicerad: Frontiers Media S.A. 2019
Ämnen:
Chemistry
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC6460053/
https://ncbi.nlm.nih.gov/pubmed/31024887
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2019.00195
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