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Electronic and steric control of n→π* interactions: stabilization of the α-helix conformation without a hydrogen bond
The preferred conformations of peptides and proteins are dependent on local interactions that bias the conformational ensemble. The n→π* interaction between consecutive carbonyls promotes compact conformations, including α-helix and polyproline II helix. In order to further understand the n→π* inter...
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| Pubblicato in: | Chembiochem |
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| Autori principali: | , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2019
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6458595/ https://ncbi.nlm.nih.gov/pubmed/30548564 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cbic.201800785 |
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