Gas/Liquid‐Phase Micro‐Flow Trifluoromethylation using Fluoroform: Trifluoromethylation of Aldehydes, Ketones, Chalcones, and N‐Sulfinylimines

A micro‐flow nucleophilic trifluoromethylation of carbonyl compounds using gaseous fluoroform was developed. This method also allows the first micro‐flow transformation of N‐sulfinylimines into trifluoromethyl amines with excellent diastereoselectivity. To demonstrate the synthetic utility of this m...

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Sparad:
Bibliografiska uppgifter
I publikationen:ChemistryOpen
Huvudupphovsmän: Hirano, Kazuki, Gondo, Satoshi, Punna, Nagender, Tokunaga, Etsuko, Shibata, Norio
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2019
Ämnen:
Communications
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC6442697/
https://ncbi.nlm.nih.gov/pubmed/30976483
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201800286
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