Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer

Acyl(chloro)phosphines RC(O)P(Cl)(t-Bu) have been prepared by formal insertion of tert-butyl phosphinidene (t-Bu–P) from t-BuPA (A = C(14)H(10) or anthracene) into the C–Cl bond of acyl chlorides. We show that the under-explored acyl(chloro)phosphine functional group provides an efficient method to...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Szkop, Kevin M., Geeson, Michael B., Stephan, Douglas W., Cummins, Christopher C.
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2019
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6432624/
https://ncbi.nlm.nih.gov/pubmed/30996956
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05657a
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