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Iron‐ and Cobalt‐Catalyzed Synthesis of Carbene Phosphinidenes
In the presence of stoichiometric or catalytic amounts of [M{N(SiMe(3))(2)}(2)] (M=Fe, Co), N‐heterocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of the type (NHC)⋅PAr. The formation of (IMe(4))⋅PMes (Mes=mesityl) is also catalyzed by the phosphinide...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5064616/ https://ncbi.nlm.nih.gov/pubmed/26643712 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201508303 |
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