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Strong Exchange Coupling in a Trimetallic Radical‐Bridged Cobalt(II)‐Hexaazatrinaphthylene Complex
Reducing hexaazatrinaphthylene (HAN) with potassium in the presence of 18‐c‐6 produces [{K(18‐c‐6)}HAN], which contains the S=1/2 radical [HAN](.−). The [HAN](.−) radical can be transferred to the cobalt(II) amide [Co{N(SiMe(3))(2)}(2)], forming [K(18‐c‐6)][(HAN){Co(N′′)(2)}(3)]; magnetic measuremen...
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| Publicado no: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5071680/ https://ncbi.nlm.nih.gov/pubmed/26997130 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600694 |
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