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Single-ion anisotropy and exchange coupling in cobalt(ii)-radical complexes: insights from magnetic and ab initio studies

The concurrent effects of single-ion anisotropy and exchange interactions on the electronic structure and magnetization dynamics have been analyzed for a cobalt(ii)-semiquinonate complex. Analogs containing diamagnetic catecholate and tropolonate ligands were employed for comparison of the magnetic...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Gransbury, Gemma K., Boulon, Marie-Emmanuelle, Mole, Richard A., Gable, Robert W., Moubaraki, Boujemaa, Murray, Keith S., Sorace, Lorenzo, Soncini, Alessandro, Boskovic, Colette
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6853083/
https://ncbi.nlm.nih.gov/pubmed/31803460
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc00914k
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