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Organoiron- and Fluoride-Catalyzed Phosphinidene Transfer to Styrenic Olefins in a Stereoselective Synthesis of Unprotected Phosphiranes

[Image: see text] Catalytic phosphiranation has been achieved, allowing preparation of trans-1-R-2-phenylphosphiranes (R = t-Bu: 1-t-Bu; i-Pr: 1-i-Pr) from the corresponding dibenzo-7-(R)-7-phospha-norbornadiene (RPA, A = C(14)H(10), anthracene) and styrene in 73% and 57% isolated yields, respective...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Geeson, Michael B., Transue, Wesley J., Cummins, Christopher C.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2019
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6727668/
https://ncbi.nlm.nih.gov/pubmed/31408599
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b07069
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